Show simple item record

dc.contributor.authorChen, Shili
dc.date.accessioned2014-03-05T16:03:58Z
dc.date.available2014-03-05T16:03:58Z
dc.date.issued2002-08
dc.identifier.otherchen_shili_200208_phd
dc.identifier.urihttp://purl.galileo.usg.edu/uga_etd/chen_shili_200208_phd
dc.identifier.urihttp://hdl.handle.net/10724/29515
dc.description.abstractThe unique properties of porphyrins, such as intense light absorption and emission, electron and oxygen transporting ability, make porphyrins desirable targets to incorporate into conjugated polymers for potential applications as semiconductors, or optic-electronic devices. However, low solubility and the lack of efficient polymerization methods have hampered the exploitation of monomeric porphyrins. The focus of this research is design and synthesis of highly soluble porphyrin monomers, and investigation of polymerization methods for constructing highly conjugated, high quality porphyrin materials. The accomplishments in this work include (1) study of solubility-structure relationships in porphyrins; (2) structure design to increase porphyrin solubility in organic solvents; (3) synthesis of a group of novel porphyrin molecules with specific structure design; (4) structure analysis of soluble porphyrin molecules by X-ray crystallography; (5) synthesis of monomers for porphyrin polymerization; (6) development and comparison of polymerization methods, including palladium mediated oxidative coupling, acyclic diyne metathesis (ADIMET) and acyclic diene metathesis (ADMET). Porphyrin solubility has been increased by tens to thousands of times when compared to other alkylporphyrins in this work. Alkene and alkyne metatheses reactions, which are applied for the first time to porphyrin polymerizations, show promising results for the preparation of defect-free conjugated porphyrin polymers.
dc.languageDesign, synthesis, and structural study of porphyrin-based organic materials
dc.publisheruga
dc.rightspublic
dc.subjectPorphyrin
dc.subjectSolubility
dc.subjectConjugated Polymer
dc.subjectFacial encumbrance
dc.subjectPalladium mediated coupling reaction
dc.subjectAcyclic diyne metathesis reaction
dc.subjectAcyclic diene metathesis reaction
dc.titleDesign, synthesis, and structural study of porphyrin-based organic materials
dc.typeDissertation
dc.description.degreePhD
dc.description.departmentChemistry
dc.description.majorChemistry
dc.description.advisorRobert S. Phillips
dc.description.committeeRobert S. Phillips
dc.description.committeeThomas E. Johnson
dc.description.committeeCharles Kutal
dc.description.committeeI. Jonathan Amster
dc.description.committeeGregory H. Robinson


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record